Chemistry Of Sea Spray Particles Linked For First Time To Formation Process

2017-06-23T16:48:17+00:00 June 23, 2017|
A "film" drop (red) and "jet" drop (blue) from bursting bubble filmed 8 milliseconds apart. (Credit: Dale Stokes)

(Click to enlarge) A “film” drop (red) and “jet” drop (blue) from bursting bubble filmed 8 milliseconds apart.
(Credit: Dale Stokes)

A team of researchers led by the University of California San Diego has identified for the first time what drives the observed differences in the chemical make-up of sea spray particles ejected from the ocean by breaking waves.

(From Science Daily) — The discovery could enable researchers to better understand how ocean chemistry and physics directly influence cloud formation processes. The improved understanding could make climate models more accurate, especially since clouds are the hardest variable to portray in current simulations.

Kimberly Prather, Distinguished Chair in Atmospheric Chemistry and a faculty member in the Department of Chemistry and Biochemistry and Scripps Institution of Oceanography at UC San Diego, led the National Science Foundation-supported study. She said its key breakthrough involved showing that the drops sent airborne by breaking waves take on different chemical characteristics depending on the physical forces induced by the waves.

“It’s the first time anyone has shown that drops from seawater have different composition due to the production mechanism,” said Prather. “We are uncovering how ocean biology influences the physical production processes creating sea spray aerosol. Previous studies have focused on the processes involved in the physical production of sea sprays but our studies demonstrated that chemistry is at the heart of many ocean-atmosphere transfer processes that have profound impacts on the composition of our atmosphere as well as clouds and climate.”

Some sea spray aerosols are “film” drops that are laden with microbes or organic material that collects on the ocean surface. They form when bubbles at the ocean surface rupture. Researchers had largely assumed that all aerosols smaller than a micron in size were of this variety. Prather and other researchers showed, however, that there are other cloud-forming particles derived from “jet” drops that are predominantly comprised of very different chemical species including sea salt, microbes, and other biological species. These new drops are ejected in the aftermath of bubbles popping.

These two types of aerosols have different capabilities for forming ice crystals in clouds, meaning that whether a cloud actually produces no precipitation, rain, or snow can be determined by the type of microbes and associated biomolecules being ejected from the ocean. More importantly, the presence of a large bloom of phytoplankton, as happens during red tide events, alters the ratio of film to jet drops, meaning biological processes can lead to profound changes in sea spray chemistry and ultimately cloud formation.

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